Ultrafast reaction dynamics and solvent effects
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Ultrafast reaction dynamics and solvent effects Royaumont, France 1993

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Published by American Institute of Physics in New York .
Written in English

Subjects:

  • High resolution spectroscopy -- Congresses.,
  • Chemical reaction, Conditions and laws of -- Congresses.,
  • Solvation -- Congresses.,
  • Molecular dynamics -- Congresses.,
  • Charge transfer -- Congresses.

Book details:

Edition Notes

Statementeditors, Yann Gauduel, Peter J. Rossky.
SeriesAIP conference proceedings -- 298., AIP conference proceedings -- no. 298.
ContributionsGauduel, Yann., Rossky, Peter J.
The Physical Object
Paginationx, 564 p. :
Number of Pages564
ID Numbers
Open LibraryOL18010838M
ISBN 101563962802
LC Control Number93074354

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The solvent dependence of the oscillation amplitude suggests the presence of vibrationally impulsive internal conversion for the fastest reaction, RuRu in water. Extremely slow solvent dynamics are observed in the slow solvents despite a very short excited-state lifetime which indicates a solvent response outside the regime of linear by: Find many great new & used options and get the best deals for Understanding Chemical Reactivity: Ultrafast Dynamics of Chemical Systems 7 (, Hardcover) at the best online prices at eBay! Free shipping for many products! Request PDF | Solvent Effects on Vibrational Coherence and Ultrafast Reaction Dynamics in the Multicolor Pump−Probe Spectroscopy of Intervalence . Exact quantum dynamics study of the O++H2(v=0,j=0)→OH++H ion-molecule reaction and comparison with quasiclassical trajectory calculations. The Journal of Chemical Physics, Vol. , Issue. 14, p. Author: Raphael D. Levine.

  However, if Li-solvent complexes undergo fast solvent exchange dynamics resulting in ultrafast fluctuation of coordination number and solvation structure, the conventional view on the robust and Cited by: Ultrafast intermolecular electron transfer much faster than solvent relaxation times has been observed and this revealed the importance of nuclear motion to this reaction. The substituent and deuterium isotope effects on the rate of electron transfer was by: 1. The dynamics are compared to previously determined oxidative addition rate constants. Next, an IPP and linear infrared spectroscopic study was performed on VC-I2 and VC-O2 in two different sets of binary solvent mixtures. The vibrational lifetime changes linearly with solvent : Brynna Halley Jones. Maroncelli M, Kumar PV, Papazyan A, Horng ML, Rosenthal SJ, Fleming GR () Studies of the inertial component of polar solvation dynamics. In: Gauduel Y, Rossky PJ (eds) Ultrafast reaction dynamics and solvent effects. AIP, New York, pp – Google Scholar.

Because of the absence of an H/D isotope effect on the forward electron transfer reaction of C in AN, hydrogen bonds are understood to play a minor role in mediating electron transfer. In contrast, direct π-orbital overlap between C and the aromatic amine solvents causes ultrafast forward electron transfer by: This book brings together many different relaxation phenomena in liquids under a common umbrella and provides a unified view of apparently diverse phenomena. It aligns recent experimental results obtained with modern techniques with recent theoretical developments. Such close interaction between experiment and theory in this area goes back to the works of .   Ultrafast X-ray spectroscopies enable the investigation of fast chemical dynamics with time resolutions reaching the order of attoseconds. Processes such as spin crossover, structural deformations Cited by:   Solvent effects on the ultrafast dynamics and spectroscopy of the charge-transfer-to-solvent reaction of sodide J. Chem. Phys. , ( in Ultrafast Dynamics of Chemical Systems, edited by J. D. Simon Cited by: